Just 40 miles east of Orlando, you'll find 72 miles of picturesque Atlantic beaches known as Florida's Space Coast. Along this impressive stretch of coastline, unspoiled nature preserves exist in perfect harmony with the space-age attractions of Kennedy Space Centre Visitor Complex, Port Canaveral and the U.S. Astronaut Hall of Fame.

The best site to bookmark for a launch schedule is this one:

http://www.spaceflightnow.com/tracking/

And look for the ones that say "Cape Canaveral."

2011 - Right now there are shuttle launches slated for : April 19 - Endeavour.

There are unmanned launches, which are cool to see too. You might get lucky with one of those, but like the shuttle they can be postponed at any time so keep checking back –

Delta 4 launches - March 11, June 23 & Dec.

Delta 2 launches - Sept 8.

Atlas 5 launches - March 4, May 4, Aug 5 & Nov 25.

Falcon 9 (Launching the Dragon spacecraft to supply the international Spacestation - July 15, Oct 8 & Dec 7.

Also the launch viewing guide should help too:

http://www.launchphotography.com/